Investigations into carbon nanotubes within the Polymer
Group first began in 1995. Since then, the programme has expanded rapidly
and nanotubes now form a major component of research within the group, under
the supervision of
Prof. Alan Windle. A list of our nanotube publications can be obtained
here.
Carbon nanotubes
are an exciting allotrope of carbon that was only fully recognised ten
years ago, and are generally considered to belong to the fullerene family.
A wide range of applications have been suggested including nanoelectronics,
ultrastrong materials (
2
), field emission guns (
3
) and catalyst supports. Within the nanotube team, we are currently investigating
the use of nanotubes in electrochemical
supercapacitor electrodes
*, nanotube arrays for gas
filration
* and
storage
*, and nanotube-modified polymer
composites
*. One of the current limiting factors on the development of such applications
is the limited quantity of high quality nanotubes that are available from
current
production routes
, and hence we have a major program developing
large-scale synthesis
* techniques. Many applications will also require
surface modification
* of nanotubes in order to control their interactions with each other
and with other functional materials.
Due to their molecular dimensions and (admitedly modest) flexibility we
belive that nanotubes, especially the single-walled variety can be regarded
as conjugated polymer molecules. In our previous work we have found evidence
that nanotubes can behave in a similar fashion to polymers under certain
circumstances and we expect further examples of polymeric phenomena to emerge.
We are very interested in exploring the interactions within mixtures of nanotubes
and conventional polymers which can be thought of as polymer blends. (
More on nanotubes as polymers
)
In addition we are combining two major strengths of the polymer group,
in terms of computational modelling of macromolecules and understanding
of nanotube behviour, to develop a